Radic GP, Glodovic VV, Kaluderovic GN, Heinemann FW, Trifunovic SR (2011)
Publication Status: Published
Publication Type: Journal article
Publication year: 2011
Publisher: SPRINGER
Book Volume: 36
Pages Range: 331-336
Journal Issue: 4
DOI: 10.1007/s11243-011-9473-3
The reaction of K-2[PdCl4] with [(S,S)-H-2(Et)(2)eddv]Cl-2 diester (O,O'-diethyl-(S,S)-ethylenediamine-N,N'-di(2)-(3-methyl)butanoate) (1) resulted in [PdCl2{(S, S)-(Et) eddv-kappa N-2,N', kappa O}] (2) complex with one hydrolyzed ester group. The compound was characterized by spectroscopic methods and it was found that the reaction is diastereoselective (H-1 and C-13 NMR; one diastereoisomer of four possible). In addition, the structure of 2 was confirmed by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N'-configured isomer. DFT calculations support the formation of one diastereoisomer of 2.
APA:
Radic, G.P., Glodovic, V.V., Kaluderovic, G.N., Heinemann, F.W., & Trifunovic, S.R. (2011). Palladium(II) complexes with R(2)edda-derived ligands. Part V. Reaction of O,O '-diethyl-(S,S)-ethylenediamine-N,N '-di-2-(3-methyl)butanoate with K-2[PdCl4]. Transition Metal Chemistry, 36(4), 331-336. https://doi.org/10.1007/s11243-011-9473-3
MLA:
Radic, Gordana P., et al. "Palladium(II) complexes with R(2)edda-derived ligands. Part V. Reaction of O,O '-diethyl-(S,S)-ethylenediamine-N,N '-di-2-(3-methyl)butanoate with K-2[PdCl4]." Transition Metal Chemistry 36.4 (2011): 331-336.
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