CHEMISTRY OF POLYFUNCTIONAL MOLECULES .11. FORMATION AND COMPLEX STABILIZATION OF A NEW CHAIN-LIKE PHOSPHAZENE ANION BY CO(II)-ASSISTED OXIDATIVE SCRAMBLING OF [N(PPH2)2]-

Ellermann J, Sutter J, Knoch F, Moll M (1993)

Publication Status: Published

Publication Type: Journal article

Publication year: 1993

Journal

Angewandte Chemie International Edition Wiley

Book Volume: 32

Pages Range: 700-701

Journal Issue: 5

Abstract

Cobalt(II) chloride acts as an oxidizing agent toward lithium bis(diphenylphosphino)amide! Surprisingly, in boiling toluene the two components (molar ratio 1:2) form a phosphazene anion with scrambling of the amide, which reacts further with cobalt(II) to give the spirocyclic metallaphosphazene 1.

Authors with CRIS profile

Jörg Sutter Lehrstuhl für Anorganische und Allgemeine Chemie Matthias Moll Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Ellermann, J., Sutter, J., Knoch, F., & Moll, M. (1993). CHEMISTRY OF POLYFUNCTIONAL MOLECULES .11. FORMATION AND COMPLEX STABILIZATION OF A NEW CHAIN-LIKE PHOSPHAZENE ANION BY CO(II)-ASSISTED OXIDATIVE SCRAMBLING OF [N(PPH2)2]-. Angewandte Chemie International Edition, 32(5), 700-701.

MLA:

Ellermann, J., et al. "CHEMISTRY OF POLYFUNCTIONAL MOLECULES .11. FORMATION AND COMPLEX STABILIZATION OF A NEW CHAIN-LIKE PHOSPHAZENE ANION BY CO(II)-ASSISTED OXIDATIVE SCRAMBLING OF [N(PPH2)2]-." Angewandte Chemie International Edition 32.5 (1993): 700-701.

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