Visible light induced reversible extrusion of nitric oxide from a ruthenium(II) nitrosyl complex: a facile delivery of nitric oxide.

Heinemann FW (2005)

Publication Status: Published

Publication Type: Journal article

Publication year: 2005

Journal

Journal of the American Chemical Society American Chemical Society

Book Volume: 127

Pages Range: 13758-13759

Journal Issue: 40

DOI: 10.1021/ja053758x

Abstract

The new ruthenium compound [Ru(NO)(pysiS4)]Br (3) (pysiS4 = 2,6-bis(3-triphenylsilyl-2-sulfanylphenylthiomethyl)pyridine), containing sterically bulky SiPh3 groups ortho to the thiolate donors, has been synthesized. In solution, 3 releases NO efficiently on exposure to visible light (lambda >/= 455 nm) at room temperature to afford [Ru(Br)(pysiS4)] (4). Treatment of 4 with NO yielded exclusively 3 without any metal-bound side reaction.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Heinemann, F.W. (2005). Visible light induced reversible extrusion of nitric oxide from a ruthenium(II) nitrosyl complex: a facile delivery of nitric oxide. Journal of the American Chemical Society, 127(40), 13758-13759. https://doi.org/10.1021/ja053758x

MLA:

Heinemann, Frank Wilhelm. "Visible light induced reversible extrusion of nitric oxide from a ruthenium(II) nitrosyl complex: a facile delivery of nitric oxide." Journal of the American Chemical Society 127.40 (2005): 13758-13759.

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