Bart SC, Heinemann FW, Anthon C, Hauser C, Meyer K (2009)
Publication Type: Journal article, Original article
Publication year: 2009
Original Authors: Bart S.C., Heinemann F.W., Anthon C., Hauser C., Meyer K.
Publisher: American Chemical Society
Book Volume: 48
Pages Range: 9419-9426
Journal Issue: 19
DOI: 10.1021/ic9012697
The synthesis of a potentially redox active tripodal ligand containing a tris(aryloxide) functionalized mesitylene anchor, (( ArOH) mes) (1), and its metalation with low-valent uranium to form [(( ArO) mes)U] (1-U) Is reported. The results from characterization by X-ray crystallography, spectroscopic studies, and computational analysis, as well as Initial reactivity studies, support a +3 uranium oxidation state. Comparison to the previously synthesized complex, [(( ArO) tacn)U] (2-U), featuring the redox-lnnocent triazacyclononane anchor reveals that changing the anchor from the flexible trlazacyclononane to a rigid mesityl fragment increases the structural flexibility of the aryloxide substituents in complexes of 1. The synthesis and crystal structures of uranium(IV) amide complexes of 1-U and 2-U are discussed. © 2009 American Chemical Society.
APA:
Bart, S.C., Heinemann, F.W., Anthon, C., Hauser, C., & Meyer, K. (2009). A new tripodal ligand system with steric and electronic modularity for uranium coordination chemistry. Inorganic Chemistry, 48(19), 9419-9426. https://doi.org/10.1021/ic9012697
MLA:
Bart, Suzanne C., et al. "A new tripodal ligand system with steric and electronic modularity for uranium coordination chemistry." Inorganic Chemistry 48.19 (2009): 9419-9426.
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