Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent

Bowman AC, Bart SC, Heinemann FW, Meyer K, Chirik PJ (2009)

Publication Type: Journal article, Original article

Publication year: 2009

Journal

Inorganic Chemistry American Chemical Society

Original Authors: Bowman A.C., Bart S.C., Heinemann F.W., Meyer K., Chirik P.J.

Publisher: American Chemical Society

Book Volume: 48

Pages Range: 5587-5589

Journal Issue: 13

DOI: 10.1021/ic9003017

Abstract

Addition of the [NH] transfer reagent Hdbabh (dbabh = 2,3:5,6-dibenzo-7- azabicyelo[2.2.1]hepta-2,5-diene) to the bis(imino)pyr-idine iron bis(dinitrogen) complex, ( PDI)Fe(N ) ( PDI = 2,6-(2,6 Pr C H N=CMe) C H N), furnished the corresponding iron amide and ammonia compounds, resulting from cleavage of the strained amine. Isotopic labeling studies support N-H bond activation by a transient, parent imide, [( PDI)FeNH]. © 2009 American Chemical Society.

Authors with CRIS profile

Frank Wilhelm Heinemann Lehrstuhl für Anorganische und Allgemeine Chemie Karsten Meyer Lehrstuhl für Anorganische und Allgemeine Chemie

How to cite

APA:

Bowman, A.C., Bart, S.C., Heinemann, F.W., Meyer, K., & Chirik, P.J. (2009). Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent. Inorganic Chemistry, 48(13), 5587-5589. https://doi.org/10.1021/ic9003017

MLA:

Bowman, A. C., et al. "Synthesis of bis(imino)pyridine iron amide and ammonia compounds from an N-H transfer agent." Inorganic Chemistry 48.13 (2009): 5587-5589.

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