Sellmann D, Geipel F, Heinemann FW (2000)
Publication Status: Published
Publication Type: Journal article
Publication year: 2000
Publisher: WILEY-V C H VERLAG GMBH
Pages Range: 59-63
Journal Issue: 1
Reaction of the trinuclear [M('S-3')](3) complexes {M = Ni (4), Pd (5), Pt (6); 'S-3'(2-) = bis (2-mercaptophenyl) sulfide (2-)} with HNPnPr(3) yielded the new phosphorane inline complexes [M(NHPnPr(3))('S-3')] {M = Ni (1), Pd (2), Pt (3)}. The complexes 1-3 have been completely characterized and are rare examples of mononuclear phosphorane imine complexes with late transition metals. Spectroscopic and structural results indicate that the HNPnPr(3) ligands favor the ylidic structure when binding to [M('S-3')] fragments. X-ray structure determinations showed that [M(NHPrP3)('S-3')] complexes associate through N-H ... S(thiolate) bridges to give centrosymmetric dimers.
APA:
Sellmann, D., Geipel, F., & Heinemann, F.W. (2000). Transition metal complexes with sulfur ligands, 140 - Mononuclear Ni, Pd and Pt complexes with ' S-3 '(2-) thioether thiolate and HNPnPr(3) phosphorane imine ligands [' S-3 '(2-) = bis(2-mercaptophenyl])sulfide (2-)]. European Journal of Inorganic Chemistry, 1, 59-63.
MLA:
Sellmann, Dieter, Franz Geipel, and Frank Wilhelm Heinemann. "Transition metal complexes with sulfur ligands, 140 - Mononuclear Ni, Pd and Pt complexes with ' S-3 '(2-) thioether thiolate and HNPnPr(3) phosphorane imine ligands [' S-3 '(2-) = bis(2-mercaptophenyl])sulfide (2-)]." European Journal of Inorganic Chemistry 1 (2000): 59-63.
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