Solid-state NMR investigations of SILP-based catalysts (B05) (SFB 1452 CLINT B05)
Third Party Funds Group - Sub project
Acronym: SFB 1452 CLINT B05
Start date : 01.01.2021
End date : 31.12.2024
Overall project details
Overall project
Catalysis at Liquid Interfaces (CLINT) (SFB 1452 CLINT)
Jan. 1, 2021 - Dec. 31, 2024
Project details
Scientific Abstract
Scientific Abstract
Project B05 aims at understanding the properties of the liquid/solid interface of Interface-enhanced SILPs using solid-state NMR spectroscopy. We will determine the dynamics of the IL and its interactions with the support, as well as the distance between the catalyst and the support by implementing advanced solid-state NMR methods, including 2D heteronuclear correlation and REDOR techniques. Ultimately, Parahydrogen Induced Polarisation (PHIP) in a Magic Angle Spinning probe will be developed as a novel tool to probe with enhanced sensitivity hy-drogenation reactions in SILP catalysts in situ and operando. Active catalyst components, reaction intermediates and side products can thus be identified.
